Special Cases
Pi bonds do not necessarily connect a pair of atoms that are also sigma-bonded.
In certain metal complexes, pi interactions between a metal atom and alkyne and alkene pi antibonding orbitals form pi-bonds.
In some cases of multiple bonds between two atoms, there is no sigma bond at all, only pi bonds. Examples include diiron hexacarbonyl (Fe2(CO)6), dicarbon (C2), and the borane B2H2. In these compounds the central bond consists only of pi bonding, and in order to achieve maximum orbital overlap the bond distances are much shorter than expected.
Read more about this topic: Pi Bond
Famous quotes containing the words special and/or cases:
“In England and America a beard usually means that its owner would rather be considered venerable than virile; on the continent of Europe it often means that its owner makes a special claim to virility.”
—Rebecca West (1892–1983)
“The world men inhabit ... is rather bleak. It is a world full of doubt and confusion, where vulnerability must be hidden, not shared; where competition, not co-operation, is the order of the day; where men sacrifice the possibility of knowing their own children and sharing in their upbringing, for the sake of a job they may have chosen by chance, which may not suit them and which in many cases dominates their lives to the exclusion of much else.”
—Anna Ford (b. 1943)