As A Homogeneous Space
The set of orthonormal bases for a space is a principal homogeneous space for the orthogonal group O(n), and is called the Stiefel manifold of orthonormal n-frames.
In other words, the space of orthonormal bases is like the orthogonal group, but without a choice of base point: given an orthogonal space, there is no natural choice of orthonormal basis, but once one is given one, there is a one-to-one correspondence between bases and the orthogonal group. Concretely, a linear map is determined by where it sends a given basis: just as an invertible map can take any basis to any other basis, an orthogonal map can take any orthogonal basis to any other orthogonal basis.
The other Stiefel manifolds for of incomplete orthonormal bases (orthonormal k-frames) are still homogeneous spaces for the orthogonal group, but not principal homogeneous spaces: any k-frame can be taken to any other k-frame by an orthogonal map, but this map is not uniquely determined.
Read more about this topic: Orthonormal Basis
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