Nernst Equation - Relation To Equilibrium

Relation To Equilibrium

At equilibrium, E = 0 and Q = K. Therefore

\begin{align} 0 &= E^o - \frac{RT}{nF} \ln K\\ \ln K &= \frac{nFE^o}{RT} \end{align}

Or at standard temperature,

We have thus related the standard electrode potential and the equilibrium constant of a redox reaction.

Read more about this topic:  Nernst Equation

Famous quotes containing the words relation to, relation and/or equilibrium:

    “Light is meaningful only in relation to darkness, and truth presupposes error. It is these mingled opposites which people our life, which make it pungent, intoxicating. We only exist in terms of this conflict, in the zone where black and white clash.”
    —Louis Aragon (1897–1982)

    “Science is the language of the temporal world; love is that of the spiritual world. Man, indeed, describes more than he explains; while the angelic spirit sees and understands. Science saddens man; love enraptures the angel; science is still seeking, love has found. Man judges of nature in relation to itself; the angelic spirit judges of it in relation to heaven. In short to the spirits everything speaks.”
    —Honoré De Balzac (1799–1850)

    “There is a relation between the hours of our life and the centuries of time. As the air I breathe is drawn from the great repositories of nature, as the light on my book is yielded by a star a hundred millions of miles distant, as the poise of my body depends on the equilibrium of centrifugal and centripetal forces, so the hours should be instructed by the ages and the ages explained by the hours.”
    —Ralph Waldo Emerson (1803–1882)