Dirac's Quantization
One of the defining advances in quantum theory was Paul Dirac's work on developing a relativistic quantum electromagnetism. Before his formulation, the presence of electric charge was simply "inserted" into the equations of quantum mechanics (QM), but in 1931 Dirac showed that a discrete charge naturally "falls out" of QM. That is to say, we can maintain the form of Maxwell's equations and still have magnetic charges.
Consider a system consisting of a single stationary electric monopole (an electron, say) and a single stationary magnetic monopole. Classically, the electromagnetic field surrounding them has a momentum density given by the Poynting vector, and it also has a total angular momentum, which is proportional to the product qeqm, and independent of the distance between them.
Quantum mechanics dictates, however, that angular momentum is quantized in units of ħ, so therefore the product qeqm must also be quantized. This means that if even a single magnetic monopole existed in the universe, and the form of Maxwell's equations is valid, all electric charges would then be quantized.
What are the units in which magnetic charge would be quantized? Although it would be possible simply to integrate over all space to find the total angular momentum in the above example, Dirac took a different approach. This led him to new ideas. He considered a point-like magnetic charge whose magnetic field behaves as qm / r 2 and is directed in the radial direction, located at the origin. Because the divergence of B is equal to zero almost everywhere, except for the locus of the magnetic monopole at r = 0, one can locally define the vector potential such that the curl of the vector potential A equals the magnetic field B.
However, the vector potential cannot be defined globally precisely because the divergence of the magnetic field is proportional to the Dirac delta function at the origin. We must define one set of functions for the vector potential on the "northern hemisphere" (the half-space z > 0 above the particle), and another set of functions for the "southern hemisphere". These two vector potentials are matched at the "equator" (the plane z = 0 through the particle), and they differ by a gauge transformation. The wave function of an electrically-charged particle (a "probe charge") that orbits the "equator" generally changes by a phase, much like in the Aharonov–Bohm effect. This phase is proportional to the electric charge qe of the probe, as well as to the magnetic charge qm of the source. Dirac was originally considering an electron whose wave function is described by the Dirac equation.
Because the electron returns to the same point after the full trip around the equator, the phase φ of its wave function exp(iφ) must be unchanged, which implies that the phase φ added to the wave function must be a multiple of 2π:
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Units Condition Gaussian-cgs units SI units (weber convention) SI units (ampere·meter convention)
where ε0 is the vacuum permittivity, ħ = h/2π is the reduced Planck's constant, c is the speed of light, and ℤ is the set of integers.
This is known as the Dirac quantization condition. The hypothetical existence of a magnetic monopole would imply that the electric charge must be quantized in certain units; also, the existence of the electric charges implies that the magnetic charges of the hypothetical magnetic monopoles, if they exist, must be quantized in units inversely proportional to the elementary electric charge.
At the time it was not clear if such a thing existed, or even had to. After all, another theory could come along that would explain charge quantization without need for the monopole. The concept remained something of a curiosity. However, in the time since the publication of this seminal work, no other widely accepted explanation of charge quantization has appeared. (The concept of local gauge invariance—see gauge theory below—provides a natural explanation of charge quantization, without invoking the need for magnetic monopoles; but only if the U(1) gauge group is compact, in which case we will have magnetic monopoles anyway.)
If we maximally extend the definition of the vector potential for the southern hemisphere, it will be defined everywhere except for a semi-infinite line stretched from the origin in the direction towards the northern pole. This semi-infinite line is called the Dirac string and its effect on the wave function is analogous to the effect of the solenoid in the Aharonov–Bohm effect. The quantization condition comes from the requirement that the phases around the Dirac string are trivial, which means that the Dirac string must be unphysical. The Dirac string is merely an artifact of the coordinate chart used and should not be taken seriously.
The Dirac monopole is a singular solution of Maxwell's equation (because it requires removing the worldline from spacetime); in more complicated theories, it is superseded by a smooth solution such as the 't Hooft–Polyakov monopole.
Read more about this topic: Magnetic Monopole