Le Chatelier's Principle - Status As A Physical Law

Status As A Physical Law

Le Chatelier's principle qualitatively describes systems of non-instantaneous change; the duration of adjustment depends on the strength of the negative feedback to the initial shock. Where a shock initially induces positive feedback (such as thermal runaway), the new equilibrium can be far from the old one, and can take a long time to reach. In some dynamic systems, the end-state cannot be determined from the shock. The principle is typically used to describe closed negative-feedback systems, but applies, in general, to thermodynamically closed and isolated systems in nature, since the second law of thermodynamics ensures that the disequilibrium caused by an instantaneous shock must have a finite half-life. The principle has analogs throughout Systems theory.

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