History
Coordination complexes were known – although not understood in any sense – since the beginning of chemistry, e.g. Prussian blue and copper vitriol. The key breakthrough occurred when Alfred Werner proposed in 1893 that Co(III) bears six ligands in an octahedral geometry. His theory allows one to understand the difference between coordinated and ionic in a compound, for example chloride in the cobalt ammine chlorides and to explain many of the previously inexplicable isomers.
In 1914, Werner resolved the first coordination complex, called hexol, into optical isomers, overthrowing the theory that only carbon compounds could possess chirality.
Read more about this topic: Coordination Complex
Famous quotes containing the word history:
“The history of any nation follows an undulatory course. In the trough of the wave we find more or less complete anarchy; but the crest is not more or less complete Utopia, but only, at best, a tolerably humane, partially free and fairly just society that invariably carries within itself the seeds of its own decadence.”
—Aldous Huxley (1894–1963)
“It takes a great deal of history to produce a little literature.”
—Henry James (1843–1916)
“I think that Richard Nixon will go down in history as a true folk hero, who struck a vital blow to the whole diseased concept of the revered image and gave the American virtue of irreverence and skepticism back to the people.”
—William Burroughs (b. 1914)