History
Coordination complexes were known – although not understood in any sense – since the beginning of chemistry, e.g. Prussian blue and copper vitriol. The key breakthrough occurred when Alfred Werner proposed in 1893 that Co(III) bears six ligands in an octahedral geometry. His theory allows one to understand the difference between coordinated and ionic in a compound, for example chloride in the cobalt ammine chlorides and to explain many of the previously inexplicable isomers.
In 1914, Werner resolved the first coordination complex, called hexol, into optical isomers, overthrowing the theory that only carbon compounds could possess chirality.
Read more about this topic: Coordination Complex
Famous quotes containing the word history:
“Only the history of free peoples is worth our attention; the history of men under a despotism is merely a collection of anecdotes.”
—Sébastien-Roch Nicolas De Chamfort (1741–1794)
“The second day of July 1776, will be the most memorable epoch in the history of America. I am apt to believe that it will be celebrated by succeeding generations as the great anniversary festival. It ought to be commemorated, as the day of deliverance, by solemn acts of devotion to God Almighty. It ought to be solemnized with pomp and parade, with shows, games, sports, guns, bells, bonfires and illuminations, from one end of this continent to the other, from this time forward forever more”
—John Adams (1735–1826)
“I assure you that in our next class we will concern ourselves solely with the history of Egypt, and not with the more lurid and non-curricular subject of living mummies.”
—Griffin Jay, and Reginald LeBorg. Prof. Norman (Frank Reicher)