History
Coordination complexes were known – although not understood in any sense – since the beginning of chemistry, e.g. Prussian blue and copper vitriol. The key breakthrough occurred when Alfred Werner proposed in 1893 that Co(III) bears six ligands in an octahedral geometry. His theory allows one to understand the difference between coordinated and ionic in a compound, for example chloride in the cobalt ammine chlorides and to explain many of the previously inexplicable isomers.
In 1914, Werner resolved the first coordination complex, called hexol, into optical isomers, overthrowing the theory that only carbon compounds could possess chirality.
Read more about this topic: Coordination Complex
Famous quotes containing the word history:
“Hence poetry is something more philosophic and of graver import than history, since its statements are rather of the nature of universals, whereas those of history are singulars.”
—Aristotle (384–322 B.C.)
“The history of progress is written in the blood of men and women who have dared to espouse an unpopular cause, as, for instance, the black man’s right to his body, or woman’s right to her soul.”
—Emma Goldman (1869–1940)
“A man will not need to study history to find out what is best for his own culture.”
—Henry David Thoreau (1817–1862)