Crystal field theory (CFT) is a model that describes the breaking of degeneracies of electronic orbital states, usually d or f orbitals, due to a static electric field produced by a surrounding charge distribution (anion neighbors). This theory has been used to describe various spectroscopies of transition metal coordination complexes, in particular optical spectra (colours). CFT successfully accounts for some magnetic properties, colours, hydration enthalpies, and spinel structures of transition metal complexes, but it does not attempt to describe bonding. CFT was developed by physicists Hans Bethe and John Hasbrouck van Vleck in the 1930s. CFT was subsequently combined with molecular orbital theory to form the more realistic and complex ligand field theory (LFT), which delivers insight into the process of chemical bonding in transition metal complexes.
Read more about Crystal Field Theory: Overview of Crystal Field Theory Analysis, Crystal Field Stabilization Energy, Explaining The Colors of Transition Metal Complexes, Crystal Field Splitting Diagrams
Famous quotes containing the words crystal, field and/or theory:
“We have ... a thirst unquenchable, to allay which he has not shown us the crystal springs. This thirst belongs to the immortality of Man.... It is no mere appreciation of the Beauty before us—but a wild effort to reach the Beauty above.”
—Edgar Allan Poe (1809–1849)
“When it had long since outgrown his purely medical implications and become a world movement which penetrated into every field of science and every domain of the intellect: literature, the history of art, religion and prehistory; mythology, folklore, pedagogy, and what not.”
—Thomas Mann (1875–1955)
“Frankly, these days, without a theory to go with it, I can’t see a painting.”
—Tom Wolfe (b. 1931)