Crystal field theory (CFT) is a model that describes the breaking of degeneracies of electronic orbital states, usually d or f orbitals, due to a static electric field produced by a surrounding charge distribution (anion neighbors). This theory has been used to describe various spectroscopies of transition metal coordination complexes, in particular optical spectra (colours). CFT successfully accounts for some magnetic properties, colours, hydration enthalpies, and spinel structures of transition metal complexes, but it does not attempt to describe bonding. CFT was developed by physicists Hans Bethe and John Hasbrouck van Vleck in the 1930s. CFT was subsequently combined with molecular orbital theory to form the more realistic and complex ligand field theory (LFT), which delivers insight into the process of chemical bonding in transition metal complexes.
Read more about Crystal Field Theory: Overview of Crystal Field Theory Analysis, Crystal Field Stabilization Energy, Explaining The Colors of Transition Metal Complexes, Crystal Field Splitting Diagrams
Famous quotes containing the words crystal, field and/or theory:
“It is crystal clear to me that if Arabs put down a draft resolution blaming Israel for the recent earthquake in Iran it would probably have a majority, the U.S. would veto it and Britain and France would abstain.”
—Amos Oz (b. 1939)
“Give me the splendid silent sun
with all his beams full-dazzling,
Give me juicy autumnal fruit ripe and red from the orchard,
Give me a field where the unmow’d grass grows,
Give me an arbor, give me the trellis’d grape,
Give me fresh corn and wheat, give me serene-moving animals teaching content,”
—Walt Whitman (1819–1892)
“Lucretius
Sings his great theory of natural origins and of wise conduct; Plato
smiling carves dreams, bright cells
Of incorruptible wax to hive the Greek honey.”
—Robinson Jeffers (1887–1962)