Trapped Atoms
The @ symbol (at sign) indicates an atom or molecule trapped inside a cage but not chemically bound to it. For example, a buckminsterfullerene (C60) with an atom (M) would simply be represented as MC60 regardless of whether M was inside the fullerene without chemical bonding or outside, bound to one of the carbon atoms. Using the @ symbol, this would be denoted M@C60 if M was inside the carbon network. A non-fullerene example is 3-, an ion in which one As atom is trapped in a cage formed by the other 32 atoms.
This notation was proposed in 1991 with the discovery of fullerene cages (endohedral fullerenes), which can trap atoms such as La to form, for example, La@C60 or La@C82. The choice of the symbol has been explained by the authors as being concise, readily printed and transmitted electronically (the at sign is included in ASCII, which most modern character encoding schemes are based on), and the visual aspects suggesting the structure of an endohedral fullerene.
Read more about this topic: Chemical Formula
Famous quotes containing the words trapped and/or atoms:
“We take refuge in illness and then are trapped there.”
—Mason Cooley (b. 1927)
“[Humanity] has unquestionably one really effective weapon—laughter. Power, money, persuasion, supplication, persecution—these can lift at a colossal humbug—push it a little—weaken it a little, century by century; but only laughter can blow it to rags and atoms at a blast. Against the assault of laughter nothing can stand.”
—Mark Twain [Samuel Langhorne Clemens] (1835–1910)