Zirconium Alloy - Formation of Hydrides and Hydrogen Embrittlement

Formation of Hydrides and Hydrogen Embrittlement

Also, 5–20% of hydrogen diffuses into the zirconium alloy cladding forming zirconium hydrides. The hydrogen production process also mechanically weakens the rods cladding because the hydrides have lower hardness, ductility and density than zirconium or its alloys, and thus blisters and cracks form upon hydrogen accumulation. This process is also known as hydrogen embrittlement.

In case of Loss-of-Coolant Accident (LOCA) in a damaged nuclear reactor, hydrogen embrittlement accelerates the degradation of the zirconium alloy cladding of the fuel rods exposed to high temperature steam.

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