Zeeman Effect - Weak Field (Zeeman Effect)

Weak Field (Zeeman Effect)

If the spin-orbit interaction dominates over the effect of the external magnetic field, and are not separately conserved, only the total angular momentum is. The spin and orbital angular momentum vectors can be thought of as precessing about the (fixed) total angular momentum vector . The (time-)"averaged" spin vector is then the projection of the spin onto the direction of :

and for the (time-)"averaged" orbital vector:

Thus,

Using and squaring both sides, we get

and: using and squaring both sides, we get

Combining everything and taking, we obtain the magnetic potential energy of the atom in the applied external magnetic field,

\begin{align} V_M &= \mu_B B m_j \left\\ &= \mu_B B m_j \left, \\ &= \mu_B B m_j g_j \end{align}

where the quantity in square brackets is the Landé g-factor gJ of the atom ( and ) and is the z-component of the total angular momentum. For a single electron above filled shells and, the Landé g-factor can be simplified into:

Read more about this topic:  Zeeman Effect

Famous quotes containing the words weak and/or field:

    “Why didst thou leave the trodden paths of men
    Too soon, and with weak hands though mighty heart
    Dare the unpastured dragon in his den?”
    —Percy Bysshe Shelley (1792–1822)

    “You cannot go into any field or wood, but it will seem as if every stone had been turned, and the bark on every tree ripped up. But, after all, it is much easier to discover than to see when the cover is off. It has been well said that “the attitude of inspection is prone.” Wisdom does not inspect, but behold.”
    —Henry David Thoreau (1817–1862)