Principal Characters in War and Peace
- Count Pyotr Kirillovich (Pierre) Bezukhov — The large-bodied, ungainly, and socially awkward illegitimate son of an old Russian grandee. Pierre, educated abroad, returns to Russia as a misfit. His unexpected inheritance of a large fortune makes him socially desirable. Pierre is the central character and often a voice for Tolstoy's own beliefs or struggles.
- Prince Andrei (Andrew) Nikolayevich Bolkonsky — A strong but cynical, thoughtful and philosophical aide-de-camp in the Napoleonic Wars.
- Princess Maria Nikolayevna Bolkonskaya — Sister of Prince Andrew, Princess Maria is a pious woman whose eccentric father attempted to give her a good education. The caring, nurturing nature of her large eyes in her otherwise thin and plain face are frequently mentioned.
- Count Ilya Andreyevich Rostov — The pater-familias of the Rostov family; terrible with finances, generous to a fault.
- Countess Natalya Rostova — Wife of Count Ilya Rostov, mother of the four Rostov children.
- Countess Natalia Ilyinichna (Natasha) Rostova — A central character, introduced as "not pretty but full of life" and a romantic young girl, she evolves through trials and suffering and eventually finds happiness. She is an accomplished singer and dancer.
- Count Nikolai Ilyich (Nicholas) Rostov — An hussar, the beloved eldest son of the Rostov family.
- Sofia Alexandrovna (Sonya) Rostova — Orphaned cousin of Vera, Nikolai, Natasha, and Petya Rostov.
- Countess Vera Ilyinichna Rostova — Eldest of the Rostov children, she marries the German career soldier, Berg.
- Pyotr Ilyich (Petya) Rostov — Youngest of the Rostov children.
- Prince Vasily Sergeyevich Kuragin — A ruthless man who is determined to marry his children well, despite having doubts about the character of some of them.
- Princess Elena Vasilyevna (Hélène) Kuragin — A beautiful and sexually alluring woman who has many affairs, including (it is rumoured) with her brother Anatole.
- Prince Anatol Vasilyevich Kuragin — Hélène's brother and a very handsome and amoral pleasure seeker who is secretly married yet tries to elope with Natasha Rostova.
- Prince Ipolit Vasilyevich — The eldest and perhaps most dim-witted of the Kuragin children.
- Prince Boris Drubetskoy — A poor but aristocratic young man driven by ambition, even at the expense of his friends and benefactors, who marries for money, rather than love, an heiress, Julie Karagina.
- Princess Anna Mikhailovna Drubetskaya — The mother of Boris.
- Fyodor Ivanovich Dolokhov — A cold, almost psychopathic officer, he ruins Nikolai Rostov by luring him into an outrageous gambling debt (by which he, Dolokhov, profits), he only shows love to his doting mother.
- Adolf Karlovich Berg — A young Russian officer, who desires to be just like everyone else.
- Anna Pavlovna Sherer — Also known as Annette, she is the hostess of the salon that is the site of much of the novel's action in Petersburg.
- Maria Dmitryevna Akhrosimova — An older Moscow society lady, she is an elegant dancer and trend-setter, despite her age and size.
- Amalia Evgenyevna Bourienne — A French woman who lives with the Bolkonskys, primarily as Princess Marya's companion.
- Vasily Dmitrich Denisov — Nikolai Rostov's friend and brother officer, who proposes to Natasha.
- Platon Krataev – The archetypal good Russian peasant, whom Pierre meets in the prisoner of war camp.
- Napoleon I of France — the Great Man, whose fate is detailed in the book.
- General Mikhail Ilarionovich Kutuzov — Russian commander-in-chief.
- Osip Bazdeyev — the Freemason who interests Pierre in his mysterious group, starting a lengthy subplot.
- Tsar Alexander I of Russia — He signed a peace treaty with Napoleon in 1807 and then went to war with him.
Many of Tolstoy's characters in War and Peace were based on real-life people known to Tolstoy himself. His grandparents and their friends were the models for many of the main characters, his great-grandparents would have been of the generation of Prince Vasilly or Count Ilya Rostov. Some of the characters, obviously, are actual historic figures.
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