Possible Mechanism
The most controversial topic in condensed matter physics has been the mechanism for high-Tc superconductivity (HTS). There have been two representative theories on the HTS. Firstly, it has been suggested that the HTS emerges by antiferromagnetic spin fluctuation in a doped system. According to this theory, the pairing wave function of the HTS should have a dx2−y2 symmetry. Thus, whether the symmetry of the pairing wave function is the d symmetry or not is essential to demonstrate on the mechanism of the HTS in respect of the spin fluctuation. That is, if HTS order parameter (pairing wave function) does not have d symmetry, then a pairing mechanism related to spin fluctuation can be ruled out. Secondly, there was the interlayer coupling model, according to which a layered structure consisting of BCS-type (s symmetry) superconductor can enhance the superconductivity by itself. By introducing an additional tunneling interaction between each layer, this model successfully explained the anisotropic symmetry of the order parameter in the HTS as well as the emergence of the HTS. Thus, in order to solve this unsettled problem, there have been numerous experiments such as photoelectron spectroscopy, NMR, specific heat measurement, etc. Unfortunately, the results were ambiguous, where some reports supported the d symmetry for the HTS but others supported the s symmetry. This muddy situation possibly originated from the indirect nature of the experimental evidence, as well as experimental issues such as sample quality, impurity scattering, twinning, etc.
Read more about this topic: Unconventional Superconductor
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