Thermodynamic System - Boundary

Boundary

A system boundary is a real or imaginary two-dimensional closed surface that encloses or demarcates the volume or region that a thermodynamic system occupies, across which quantities such as heat, mass, or work can flow. In short, a thermodynamic boundary is a geometrical division between a system and its surroundings. Topologically, it is usually considered nearly or piecewise smoothly homeomorphic with a two-sphere, because a system is usually considered simply connected.

Boundaries can also be fixed (e.g. a constant volume reactor) or moveable (e.g. a piston). For example, in a reciprocating engine, a fixed boundary means the piston is locked at its position; as such, a constant volume process occurs. In that same engine, a moveable boundary allows the piston to move in and out. Boundaries may be real or imaginary. For closed systems, boundaries are real while for open system boundaries are often imaginary. For theoretical purposes, a boundary may be declared adiabatic, isothermal, diathermal, insulating, permeable, or semipermeable—but actual physical materials that provide such idealized properties are not always readily available.

Anything that passes across the boundary that effects a change in the internal energy must be accounted for in the energy balance equation. The volume can be the region surrounding a single atom resonating energy, such as Max Planck defined in 1900; it can be a body of steam or air in a steam engine, such as Sadi Carnot defined in 1824; it can be the body of a tropical cyclone, such as Kerry Emanuel theorized in 1986 in the field of atmospheric thermodynamics; it could also be just one nuclide (i.e. a system of quarks) as hypothesized in quantum thermodynamics.