In thermodynamics, a thermodynamic system is in thermodynamic equilibrium when it is in thermal equilibrium, mechanical equilibrium, radiative equilibrium, and chemical equilibrium. Equilibrium means a state of balance. In a state of thermodynamic equilibrium, there are no net flows of matter or of energy, no phase changes, and no unbalanced potentials (or driving forces), within the system. A system that is in thermodynamic equilibrium experiences no changes when it is isolated from its surroundings.
In non-equilibrium systems there are net flows of matter or energy, or phase changes are occurring; if such changes can be triggered to occur in a system in which they are not already occurring, it is said to be in a metastable equilibrium.
Thermodynamics |
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The classical Carnot heat engine |
Branches
Classical · Statistical · Chemical Equilibrium / Non-equilibrium |
Laws Zeroth · First · Second · Third |
Systems
State: Equation of state Ideal gas · Real gas Phase of matter · Equilibrium Control volume · Instruments Read more about Thermodynamic Equilibrium: Overview, Local and Global Equilibrium, General References Famous quotes containing the word equilibrium:“That doctrine [of peace at any price] has done more mischief than any I can well recall that have been afloat in this country. It has occasioned more wars than any of the most ruthless conquerors. It has disturbed and nearly destroyed that political equilibrium so necessary to the liberties and the welfare of the world.” Related Phrases
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