Change of Internal State of An Isolated System
If an isolated system is left long enough, it will reach a state of thermal equilibrium, in which its temperature will be uniform throughout, but not necessarily a state of thermodynamic equilibrium, if there is some structural barrier that can prevent some possible processes in the system from reaching equilibrium. An isolated system can change its temperature or its spatial distribution of temperature by changing the state of Longley, R.G. Van Name, Longmans, Green & Co., New York, 1928, volume 1, pages 55-353, particularly pages 144-150. A system prepared as a mixture of petrol vapour and air can be ignited by a spark and produce carbon dioxide and water; if this happens in an isolated system, it will increase the temperature of the system, and during the increase, the system is not in thermal equilibrium; but eventually the system will settle to a uniform temperature. In a system prepared as a block of ice floating in a bath of hot water, and then isolated, the ice can melt; during the melting, the system is not in thermal equilibrium; but eventually its temperature will become uniform. Such changes in isolated systems are irreversible in the sense that while such a change will occur spontanteously whenever the system is prepared in the same way, the reverse change will never occur spontanteously within the isolated system; this is a large part of the content of the second law of thermodynamics. Truly isolated systems hardly occur in nature, and nearly always are artificially prepared.
Read more about this topic: Thermal Equilibrium
Famous quotes containing the words change of, change, internal, state, isolated and/or system:
“Indeed, I thought, slipping the silver into my purse ... what a change of temper a fixed income will bring about. No force in the world can take from me my five hundred pounds. Food, house and clothing are mine for ever. Therefore not merely do effort and labour cease, but also hatred and bitterness. I need not hate any man; he cannot hurt me. I need not flatter any man; he has nothing to give me.”
—Virginia Woolf (1882–1941)
“We black women must forgive black men for not protecting us against slavery, racism, white men, our confusion, their doubts. And black men must forgive black women for our own sometimes dubious choices, divided loyalties, and lack of belief in their possibilities. Only when our sons and our daughters know that forgiveness is real, existent, and that those who love them practice it, can they form bonds as men and women that really can save and change our community.”
—Marita Golden, educator, author. Saving Our Sons, p. 188, Doubleday (1995)
“A State, in idea, is the opposite of a Church. A State regards classes, and not individuals; and it estimates classes, not by internal merit, but external accidents, as property, birth, etc. But a church does the reverse of this, and disregards all external accidents, and looks at men as individual persons, allowing no gradations of ranks, but such as greater or less wisdom, learning, and holiness ought to confer. A Church is, therefore, in idea, the only pure democracy.”
—Samuel Taylor Coleridge (1772–1834)
“The last public hanging in the State took place in 1835 on Prince Hill.... On the fatal day, the victim, a man named Watkins, peering through the iron bars of his cell, and seeing the townfolk scurrying to the place of execution, is said to have remarked, ‘Why is everyone running? Nothing can happen until I get there.’”
—Administration for the State of Con, U.S. public relief program (1935-1943)
“An isolated outbreak of virginity ... is a rash on the face of society. It arouses only pity from the married, and embarrassment from the single.”
—Charlotte Bingham (b. 1942)
“... the yearly expenses of the existing religious system ... exceed in these United States twenty millions of dollars. Twenty millions! For teaching what? Things unseen and causes unknown!... Twenty millions would more than suffice to make us wise; and alas! do they not more than suffice to make us foolish?”
—Frances Wright (1795–1852)