Structure
Paratellurite, α-TeO2, converts at high pressure into the β-, tellurite form. Both the α-, (paratellurite) and β- (tellurite forms) contain four coordinate Te with the oxygen atoms at four of the corners of a trigonal bipyramid. In paratellurite all vertices are shared to give a rutile-like structure, where the O-Te-O bond angle are 140°. α-TeO2 In tellurite pairs of trigonal pyramidal, TeO4 units, sharing an edge, share vertices to then form a layer. The shortest Te-Te distance in tellurite is 317 pm, compared to 374 pm in paratellurite. Similar Te2O6 units are found in the mineral denningite.
TeO2 melts at 732.6 °C, forming a red liquid.
Read more about this topic: Tellurium Dioxide
Famous quotes containing the word structure:
“A committee is organic rather than mechanical in its nature: it is not a structure but a plant. It takes root and grows, it flowers, wilts, and dies, scattering the seed from which other committees will bloom in their turn.”
—C. Northcote Parkinson (1909–1993)
“It is difficult even to choose the adjective
For this blank cold, this sadness without cause.
The great structure has become a minor house.
No turban walks across the lessened floors.
The greenhouse never so badly needed paint.”
—Wallace Stevens (1879–1955)
“The syntactic component of a grammar must specify, for each sentence, a deep structure that determines its semantic interpretation and a surface structure that determines its phonetic interpretation.”
—Noam Chomsky (b. 1928)