Structural Isomer - Chain Isomerism

In chain isomerism, or skeletal isomerism, components of the (usually carbon) skeleton are distinctly re-ordered to create different structures. Pentane exists as three isomers: n-pentane (often called simply "pentane"), isopentane (2-methylbutane) and neopentane (dimethylpropane).

Skeletal isomerism of pentane
n-Pentane Isopentane Neopentane

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