In a molecule, strain energy is released when the constituent atoms are allowed to rearrange themselves in a chemical reaction or a change of chemical conformation in a way that:
- angle strain,
- torsional strain,
- ring strain and/or steric strain,
- Allylic strain, and
- pentane interference
are reduced. The external work done on an elastic member in causing it to distort from its unstressed state is transformed into strain energy which is a form of potential energy. The strain energy in the form of elastic deformation is mostly recoverable in the form of mechanical work.
For example, the heat of combustion of cyclopropane (696 kJ/mol) is higher than that of propane (657 kJ/mol) per methylene unit. Compounds with unusually large strain energy include tetrahedranes, propellanes, cubanes, fenestranes and cyclophanes.
Famous quotes containing the words strain and/or energy:
“A man who strains himself on the stage is bound, if he is any good, to strain all the people sitting in the stalls.”
—Bertolt Brecht (1898–1956)
“The principle of avoiding the unnecessary expenditure of energy has enabled the species to survive in a world full of stimuli; but it prevents the survival of the aristocracy.”
—Rebecca West (1892–1983)