Solid-state Physics - Crystal Structure and Properties

Crystal Structure and Properties

Many properties of materials are affected by their crystal structure. This structure can be investigated using a range of crystallographic techniques, including X-ray crystallography, neutron diffraction and electron diffraction.

The sizes of the individual crystals in a crystalline solid material vary depending on the material involved and the conditions when it was formed. Most crystalline materials encountered in everyday life are polycrystalline, with the individual crystals being microscopic in scale, but macroscopic single crystals can be produced either naturally (e.g. diamonds) or artificially.

Real crystals feature defects or irregularities in the ideal arrangements, and it is these defects that critically determine many of the electrical and mechanical properties of real materials.

The crystal lattice can vibrate. These vibrations are found to be quantised, the quantised vibrational modes being known as phonons. Phonons play a major role in many of the physical properties of solids, such as the transmission of sound. In insulating solids, phonons are also the primary mechanism by which heat conduction takes place. Phonons are also necessary for understanding the lattice heat capacity of a solid, as in the Einstein model and the later Debye model.

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