Smokeless Powder - Smokeless Propellant Components

Smokeless Propellant Components

The propellant formulations may contain various energetic and auxiliary components:

  • Propellants:
    • Nitrocellulose, an energetic component of most smokeless propellants
    • Nitroglycerin, an energetic component of double-base and triple-base formulations
    • Nitroguanidine, a component of triple-base formulations
    • D1NA (bis-nitroxyethylnitramine)
    • Fivonite (tetramethylolcyclopentanone)
    • DGN (di-ethylene glycol dinitrate)
    • Acetyl cellulose
  • Deterrents, (or moderants), to slow the burning rate
    • Centralites (symmetrical diphenyl urea—primarily diethyl or dimethyl)
    • Dibutyl phthalate
    • Dinitrotoluene (toxic, carcinogenic, and obsolete)
    • Akardite (asymmetrical diphenyl urea)
    • ortho-tolyl urethane
    • Polyester adipate
    • Camphor (obsolete)
  • Stabilizers, to prevent or slow down self-decomposition
    • Diphenylamine
    • Petroleum jelly
    • Calcium carbonate
    • Magnesium oxide
    • Sodium bicarbonate
    • beta-naphthol methyl ether
    • Amyl alcohol (obsolete)
    • Aniline (obsolete)
  • Decoppering additives, to hinder the buildup of copper residues from the gun barrel rifling
    • Tin metal and compounds (e.g., tin dioxide)
    • Bismuth metal and compounds (e.g., bismuth trioxide, bismuth subcarbonate, bismuth nitrate, bismuth antimonide); the bismuth compounds are favored as copper dissolves in molten bismuth, forming brittle and easily removable alloy
    • Lead foil and lead compounds, phased out due to toxicity
  • Flash reducers, to reduce the brightness of the muzzle flash (all have a disadvantage: the production of smoke)
    • Potassium chloride
    • Potassium nitrate
    • Potassium sulfate
    • Potassium hydrogen tartarate (a byproduct of wine production formerly used by French artillery)
  • Wear reduction additives, to lower the wear of the gun barrel liners
    • Wax
    • Talc
    • Titanium dioxide
    • Polyurethane jackets over the powder bags, in large guns
  • Other additives
    • Ethyl acetate, a solvent for manufacture of spherical powder
    • Rosin, a surfactant to hold the grain shape of spherical powder
    • Graphite, a lubricant to cover the grains and prevent them from sticking together, and to dissipate static electricity

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