Side Chain

In organic chemistry and biochemistry, a side chain is a chemical group that is attached to a core part of the molecule called "main chain" or backbone. The placeholder R is often used as a generic placeholder for alkyl (saturated hydrocarbon) group side chains in chemical structure diagrams. To indicate other non-carbon groups in structure diagrams, X, Y, or Z is often used. The R, historically, was introduced by 19th-century French chemist Charles Frédéric Gerhardt and may be derived from radical, or from residue and its German equivalent Rest.

In polymer science, the side chain or pendant chain is oligomeric or polymeric offshoot extends from the backbone chain of a polymer. Side chains have noteworthy influence on a polymer's properties, mainly its crystallinity and density. An oligomeric branch may be termed a short-chain branch and a polymeric branch may be termed a long-chain branch. Side groups are different from side chains; they are neither oligomeric nor polymeric.

In proteins (composed of amino acids) the side chains are attached to the alpha-carbon atoms of the amide backbone.

Famous quotes containing the words side and/or chain:

    Telephone poles were matchsticks, put there to be snapped off at a whim. Dogs trotting across the road were suddenly big trucks. Old ladies turned into moving—vans. Everything was too bright, but very funny and made for my delight. And about half a mile from my long liquid breakfast I turned carefully down a side street and parked, and sat beaming happily through the tannic fog for about an hour, remembering how witty we all had been, how handsome and talented ... [ellipsis in original]
    M.F.K. Fisher (1908–1992)

    The conclusion suggested by these arguments might be called the paradox of theorizing. It asserts that if the terms and the general principles of a scientific theory serve their purpose, i. e., if they establish the definite connections among observable phenomena, then they can be dispensed with since any chain of laws and interpretive statements establishing such a connection should then be replaceable by a law which directly links observational antecedents to observational consequents.
    —C.G. (Carl Gustav)