Ordinaries
- Gjergj Radovani (1767-1771)
- Paolo Dovanli (1771-1776)
- Andrea Canova (1851-1856)
- Francesco Domenico Raynaud (Reynaudi), O.F.M. Cap. † (12 Dec 1867 Appointed - 1885 Resigned)
- Roberto Menini, O.F.M. Cap. † (19 May 1885 Appointed - 14 Oct 1916 Died)
- Vinkenti Peev, O.F.M. Cap. † (14 Oct 1916 Succeeded - 1941 Died)
- Ivan Romanov (Catholic bishop) † (6 Jul 1942 Appointed - 1959 Died)
- Bogdan Stefanov Dobranov † (22 Jul 1975 Appointed - 4 Oct 1983 Died)
- Gheorghi Ivanov Jovcev (13 Nov 1995 Appointed - )
Read more about this topic: Roman Catholic Diocese Of Sofia And Plovdiv