Geology
These curious formations are the remnants of an ancient fold-and-thrust belt, west of the mountain core that formed in the Alleghenian orogeny (Stanley, 421-2). Here, strata have been folded westward, and forced over massive thrust faults; there is little metamorphism, and no igneous intrusion.(Stanley, 421-2) The ridges represent the edges of the erosion-resistant strata, and the valleys portray the absence of the more erodible strata. Smaller streams have developed their valleys following the lines of the more easily eroded strata. But a few major rivers, such as the Delaware River, the Susquehanna River, and the Potomac River are evidently older than the present mountains, having cut water gaps that are perpendicular to hard strata ridges. The evidence points to a wearing down of the entire region (the original mountains) to a low level with little relief, so that major rivers were flowing in unconsolidated sediments that were unaffected by the underlying rock structure. Then the region was uplifted slowly enough that the rivers were able to maintain their course, cutting through the ridges as they developed.
Valleys may be synclinal valleys or anticlinal valleys.
These mountains are at their highest development in central Pennsylvania, a phenomenon termed the Pennsylvania climax.
Read more about this topic: Ridge-and-Valley Appalachians