History
The concept of a reversible reaction was introduced by Berthollet in 1803, after he had observed the formation of sodium carbonate crystals at the edge of a salt lake (one of the natron lakes in Egypt, in limestone):
- 2NaCl + CaCO3 → Na2CO3 + CaCl2
He recognized this as the reverse of the familiar reaction
- Na2CO3 + CaCl2→ 2NaCl + CaCO3
Until then, chemical reactions were thought to always proceed in one direction. Berthollet reasoned that the excess of salt in the lake helped push the "reverse" reaction towards the formation of sodium carbonate.
In 1864, Waage and Guldberg formulated their law of mass action which quantified Berthollet's observation. Between 1884 and 1888, Le Chatelier and Braun formulated Le Chatelier's principle, which extended the same idea to a more general statement on the effects of factors other than concentration on the position of the equilibrium.
Read more about this topic: Reversible Reaction
Famous quotes containing the word history:
“Look through the whole history of countries professing the Romish religion, and you will uniformly find the leaven of this besetting and accursed principle of action—that the end will sanction any means.”
—Samuel Taylor Coleridge (1772–1834)
“My good friends, this is the second time in our history that there has come back from Germany to Downing Street peace with honour. I believe it is peace for our time. We thank you from the bottom of our hearts. And now I recommend you to go home and sleep quietly in your beds.”
—Neville Chamberlain (1869–1940)
“The visual is sorely undervalued in modern scholarship. Art history has attained only a fraction of the conceptual sophistication of literary criticism.... Drunk with self-love, criticism has hugely overestimated the centrality of language to western culture. It has failed to see the electrifying sign language of images.”
—Camille Paglia (b. 1947)