Resonance (chemistry) - Resonance Energy

Resonance Energy

Every structure is associated with a certain quantity of energy, which determines the stability of the molecule or ion (the lower energy, the greater stability). A resonance hybrid has a structure that is intermediate between the contributing structures; the total quantity of potential energy, however, is lower than the intermediate. Hybrids are therefore always more stable than any of the contributing structures would be. The molecule is sometimes said to be "stabilized by resonance" or "resonance-stabilized," but the stabilization derives from electron delocalization, of which "resonance" is only a description. Delocalization of the π-electrons lowers the orbital energies, imparting this stability. The difference between the potential energy of the actual structure (the resonance hybrid) and that of the contributing structure with the lowest potential energy is called the "resonance energy".

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