Alloy Design
Precipitation strengthening is possible if the line of solid solubility slopes strongly toward the center of a phase diagram. While a large volume of precipitate particles is desirable, a small enough amount of the alloying element should be added that it remains easily soluble at some reasonable annealing temperature.
Elements used for precipitation strengthening in typical aluminum and titanium alloys make up about 10% of their composition. While binary alloys are more easily understood as an academic exercise, commercial alloys often use three components for precipitation strengthening, in compositions such as Al(Mg, Cu) and Ti(Al, V). A large number of other constituents may be unintentional, but benign, or may be added for other purposes such as grain refinement or corrosion resistance. In some cases, such as many aluminum alloys, an increase in strength is achieved at the expense of corrosion resistance.
The addition of large amounts of nickel and chromium needed for corrosion resistance in stainless steels means that traditional hardening and tempering methods are not effective. However, precipitates of chromium, copper or other elements can strengthen the steel by similar amounts in comparison to hardening and tempering. The strength can be tailored by adjusting the annealing process, with lower initial temperatures resulting in higher strengths. The lower initial temperature increase driving force of nucleation. More driving force means more nucleation sites, and more sites, means more places for dislocations to be disrupted while the finished part is in use.
Many alloy systems allow the aging temperature to be adjusted. For instance, some aluminium alloys used to make rivets for aircraft construction are kept in dry ice from their initial heat treatment until they are installed in the structure. After this type of rivet is deformed into its final shape, aging occurs at room temperature and increases its strength, locking the structure together. Higher aging temperatures would risk over-aging other parts of the structure, and require expensive post-assembly heat treatment. Too high of an aging temperature promotes the precipitate to grow too readily.
Read more about this topic: Precipitation Hardening
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