Production
The production of pure platinum group metals normally starts from residues of the production of other metals with a mixture of several of those metals. One typical starting product is the anode residue of gold (other fast refining methods used today), copper or nickel production. The differences in chemical reactivity and solubility of several compounds of the metals under extraction are used to separate them.
A first step is to dissolve all the metals in aqua regia forming their respective Cl-complexes. If silver is present, this is then separated by forming insoluble silver chloride. Rhodium sulfate is separated after the salts have been melted together with sodium bisulfate and leached with water. The residue is then melted together with sodium peroxide, which dissolves all the metals and leaves the iridium. The two remaining metals, ruthenium and osmium, form ruthenium and osmium tetroxides after chlorine has been added to solution. The osmium tetroxide is then dissolved in alcoholic sodium hydroxide and separated from the ruthenium tetroxides. All of these metals' final chemical compounds can ultimately be reduced to the elemental metal using hydrogen.
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