Ozone-oxygen Cycle - Removal

Removal

If an oxygen atom and an ozone molecule meet, they recombine to form two oxygen molecules:

O3 + O· → 2 O2

And if two oxygen atoms meet, they react to form one oxygen molecule:

2 O· → O2

The overall amount of ozone in the stratosphere is determined by a balance between production by solar radiation, and removal. The removal rate is slow, since the concentration of O atoms is very low.

Certain free radicals, the most important being hydroxyl (OH), nitric oxide (NO), and atoms of chlorine (Cl) and bromine (Br), catalyze the recombination reaction, leading to an ozone layer that is thinner than it would be if the catalysts were not present.

Most of the OH and NO are naturally present in the stratosphere, but human activity, especially emissions of chlorofluorocarbons (CFCs) and halons, has greatly increased the Cl and Br concentrations, leading to ozone depletion. Each Cl or Br atom can catalyze tens of thousands of decomposition reactions before it is removed from the stratosphere.

Read more about this topic:  Ozone-oxygen Cycle

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