Ostwald Ripening

Ostwald ripening is an observed phenomenon in solid solutions or liquid sols which describes the change of an inhomogeneous structure over time. Over time, small crystals or sol particles dissolve, and redeposit onto larger crystals or sol particles.

Dissolution of small crystals or sol particles and the redeposition of the dissolved species on the surfaces of larger crystals or sol particles was first described by Wilhelm Ostwald in 1896. Ostwald ripening is generally found in water-in-oil emulsions, while flocculation is found in oil-in-water emulsions.