Order (chemistry) - Mixed Order

Mixed Order

In a mixed-order reaction, the order of a reaction changes in the course of a reaction as a result of changing variables such as pH. An example is the oxidation of an alcohol to a ketone by a ruthenate (RuO42−) and a hexacyanoferrate, the latter serving as the sacrificial catalyst converting Ru(IV) back to Ru(VI): the disappearing-rate of the ferrate is zero-order with respect to the ferrate at the onset of the reaction (when its concentration is high and the ruthenium catalyst is quickly regenerated) but changes to first-order when its concentration decreases.

Read more about this topic:  Order (chemistry)

Famous quotes containing the words mixed and/or order:

    But oh, not the hills of Habersham,
    And oh, not the valleys of Hall
    Avail: I am fain for to water the plain.
    Downward, the voices of Duty call—
    Downward, to toil and be mixed with the main,
    The dry fields burn, and the mills are to turn,
    And a myriad flowers mortally yearn,
    And the lordly main from beyond the plain
    Calls o’er the hills of Habersham,
    Calls through the valleys of Hall.
    Sidney Lanier (1842–1881)

    Without poets, without artists, men would soon weary of nature’s monotony. The sublime idea men have of the universe would collapse with dizzying speed. The order which we find in nature, and which is only an effect of art, would at once vanish. Everything would break up in chaos. There would be no seasons, no civilization, no thought, no humanity; even life would give way, and the impotent void would reign everywhere.
    Guillaume Apollinaire (1880–1918)