Non-equilibrium System
Because chemical diffusion is a net transport process, the system in which it takes place is not an equilibrium system (i.e. it is not at rest yet). Many results in classical thermodynamics are not easily applied to non-equilibrium systems. However, there sometimes occur so-called quasi-steady states, where the diffusion process does not change in time, where classical results may locally apply. As the name suggests, this process is a not a true equilibrium since the system is still evolving.
Non-equilibrium fluid systems can be successfully modeled with Landau-Lifshitz fluctuating hydrodynamics. In this theoretical framework, diffusion is due to fluctuations whose dimensions range from the molecular scale to the macroscopic scale.
Chemical diffusion increases the entropy of a system, i.e. diffusion is a spontaneous and irreversible process. Particles can spread out by diffusion, but will not spontaneously re-order themselves (absent changes to the system, assuming no creation of new chemical bonds, and absent external forces acting on the particle).
Read more about this topic: Molecular Diffusion
Famous quotes containing the word system:
“In a universe that is all gradations of matter, from gross to fine to finer, so that we end up with everything we are composed of in a lattice, a grid, a mesh, a mist, where particles or movements so small we cannot observe them are held in a strict and accurate web, that is nevertheless nonexistent to the eyes we use for ordinary living—in this system of fine and finer, where then is the substance of a thought?”
—Doris Lessing (b. 1919)