Mercury (planet) - Surface Conditions and "atmosphere" (exosphere)

Surface Conditions and "atmosphere" (exosphere)

The surface temperature of Mercury ranges from 100 K to 700 K due to the absence of an atmosphere and a steep temperature gradient between the equator and the poles. The subsolar point reaches about 700 K during perihelion then drops to 550 K at aphelion. On the dark side of the planet, temperatures average 110 K. The intensity of sunlight on Mercury’s surface ranges between 4.59 and 10.61 times the solar constant (1,370 W·m−2).

Although the daylight temperature at the surface of Mercury is generally extremely high, observations strongly suggest that ice (frozen water) exists on Mercury. The floors of deep craters at the poles are never exposed to direct sunlight, and temperatures there remain below 102 K; far lower than the global average. Water ice strongly reflects radar, and observations by the 70 m Goldstone telescope and the VLA in the early 1990s revealed that there are patches of very high radar reflection near the poles. While ice is not the only possible cause of these reflective regions, astronomers believe it is the most likely.

The icy regions are believed to contain about 1014–1015 kg of ice, and may be covered by a layer of regolith that inhibits sublimation. By comparison, the Antarctic ice sheet on Earth has a mass of about 4×1018 kg, and Mars' south polar cap contains about 1016 kg of water. The origin of the ice on Mercury is not yet known, but the two most likely sources are from outgassing of water from the planet’s interior or deposition by impacts of comets.

Mercury is too small and hot for its gravity to retain any significant atmosphere over long periods of time; it does have a "tenuous surface-bounded exosphere" containing hydrogen, helium, oxygen, sodium, calcium, potassium and others. This exosphere is not stable—atoms are continuously lost and replenished from a variety of sources. Hydrogen and helium atoms probably come from the solar wind, diffusing into Mercury’s magnetosphere before later escaping back into space. Radioactive decay of elements within Mercury’s crust is another source of helium, as well as sodium and potassium. MESSENGER found high proportions of calcium, helium, hydroxide, magnesium, oxygen, potassium, silicon and sodium. Water vapor is present, released by a combination of processes such as: comets striking its surface, sputtering creating water out of hydrogen from the solar wind and oxygen from rock, and sublimation from reservoirs of water ice in the permanently shadowed polar craters. The detection of high amounts of water-related ions like O+, OH-, and H₂O+ was a surprise. Because of the quantities of these ions that were detected in Mercury's space environment, scientists surmise that these molecules were blasted from the surface or exosphere by the solar wind.

Sodium, potassium and calcium were discovered in the atmosphere during the 1980–1990s, and are believed to result primarily from the vaporization of surface rock struck by micrometeorite impacts. In 2008 magnesium was discovered by MESSENGER probe. Studies indicate that, at times, sodium emissions are localized at points that correspond to the planet's magnetic poles. This would indicate an interaction between the magnetosphere and the planet's surface.