Theory
Consider a system are of localized, non-interacting absorbing centers. Based on the semi-classical radiation absorption theory within the electric dipole approximation, the electric vector of the circularly polarized waves propagates in the +z direction, where + and -denote to RCP light and LCP light respectively. In this system, ω = 2nν is the circular frequency, and Ii = n – ik is the complex refractive index. As the light travels, the attenuation of the beam is expressed as
- I(z) = I0exp(−2ωkz/c)
where k is the absorption coefficient of the medium in the z direction. Circular dichroism (CD) is then defined as Δk = k– – k+, and it follows the sign convention of natural optical activity. In the presence of the static, uniform external magnetic field, the Hamiltonian for the absorbing center takes the form Ĥ = Ĥ0 + Ĥ1 which is parallel to the direction of the propagation of the electric field k. Because the transition occur between the two eigenstates of Ĥ0, a and j, the absorption and the CD intensity are determined as follows:
Read more about this topic: Magnetic Circular Dichroism
Famous quotes containing the word theory:
“Lucretius
Sings his great theory of natural origins and of wise conduct; Plato
smiling carves dreams, bright cells
Of incorruptible wax to hive the Greek honey.”
—Robinson Jeffers (1887–1962)
“... the first reason for psychology’s failure to understand what people are and how they act, is that clinicians and psychiatrists, who are generally the theoreticians on these matters, have essentially made up myths without any evidence to support them; the second reason for psychology’s failure is that personality theory has looked for inner traits when it should have been looking for social context.”
—Naomi Weisstein (b. 1939)