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- Horace Walker (1838–1908) UK. First ascent Mount Elbrus, Grandes Jorasses, Barre des Ecrins, Obergabelhorn.
- Lucy Walker (1836–1916) UK. First female ascent Matterhorn (1871).
- Bradford Washburn (1910–2007) USA. Third ascent Denali, pioneered west buttress route.
- Barbara Washburn (born ?) USA. First ascent Mount Bertha, first female ascent Denali (1947).
- Don Whillans (1933–1985) UK. First ascent Annapurna south face (1970).
- Rick White (1946–2004) Australia. Rock climber, developed Frog Buttress (1968).
- Jim Whittaker (born 1929) USA. First US ascent Everest (1963).
- Lou Whittaker (born 1929) USA. Rainier guide.
- Edward Whymper (1840–1911) UK. First ascent Matterhorn (1865), first ascent Chimborazo (1880).
- Jim Wickwire (born 1940) USA. K2 (1978) (bivouacked near summit).
- Krzysztof Wielicki (born 1950) Poland. First winter ascent Everest; 5th person to climb all eight-thousanders.
- Karl Wien (1906–1937) Germany. Leader of unsuccessful Nanga Parbat expedition (1937).
- Fritz Wiessner (1900–1988) USA. Born Dresden, emigrated to US; pioneer of free climbing; K2 expedition (1939).
- Walter Wilcox (1869–1949) Nationality? Canadian Rockies explorer.
- George Willig (born 1949) USA. Climbed South Tower of World Trade Center.
- Fritz Wintersteller (born 1927) Austria. First ascent Broad Peak (1957) and Skil Brum (1957).
- Ian Woodall (born 1956) UK. Climbed Everest several times.
- Fanny Bullock Workman (1859–1925) USA. Geographer, cartographer and mountaineer, notably in the Himalayas.
Read more about this topic: List Of Climbers And Mountaineers
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