The lead chamber process was an industrial method used to produce sulfuric acid in large quantities. It has been largely supplanted by the contact process.
In 1746 in Birmingham, England, John Roebuck began producing sulfuric acid in lead-lined chambers, which were stronger, less expensive, and could be made much larger than the glass containers which had been used previously. This allowed the effective industrialization of sulfuric acid production and with several refinements, this process remained the standard method of production for almost two centuries. So robust was the process that as late as 1946, the chamber process accounted for 25% of sulfuric acid manufactured.
Read more about Lead Chamber Process: The Process, Chemistry, Further Reading
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