Lanthanide Contraction

Lanthanide contraction is a term used in chemistry to describe the greater than expected decrease in ionic radii of the elements in the lanthanide series from atomic number 58, cerium, to 71, lutetium, which results in smaller than otherwise expected ionic radii for the subsequent elements starting with 72, hafnium. The term was coined by the Norwegian geochemist Victor Goldschmidt in his series "Geochemische Verteilungsgesetze Der Elemente".

Element Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Atomic electron configuration
4f15d16s2 4f36s2 4f46s2 4f56s2 4f66s2 4f76s2 4f75d16s2 4f96s2 4f106s2 4f116s2 4f126s2 4f136s2 4f146s2 4f145d16s2
Ln3+ electron configuration 4f1 4f2 4f3 4f4 4f5 4f6 4f7 4f8 4f9 4f10 4f11 4f12 4f13

4f14

Ln3+ radius (pm) (6-coordinate) 102 99 98.3 97 95.8 94.7 93.8 92.3 91.2 90.1 89 88 86.8 86.1

Read more about Lanthanide Contraction:  Cause, Effects