Original Statements
Gustav Kirchhoff stated his law in several papers in 1859 and 1860, and then in 1862 in an appendix to his collected reprints of those and some related papers.
Prior to Kirchhoff's studies, it was known that for total heat radiation, the ratio of emissive power to absorptive ratio was the same for all bodies emitting and absorbing thermal radiation in thermodynamic equilibrium. This means that a good absorber is a good emitter. Naturally, a good reflector is a poor absorber. For wavelength specificity, prior to Kirchhoff, the ratio was shown experimentally by Balfour Stewart to be the same for all bodies, but the universal value of the ratio had not been explicitly considered in its own right as a function of wavelength and temperature.
Kirchhoff's original contribution to the physics of thermal radiation was his postulate of a perfect black body radiating and absorbing thermal radiation in an enclosure opaque to thermal radiation and with walls that absorb at all wavelengths. Kirchhoff's perfect black body absorbs all the radiation that falls upon it.
Every such black body emits from its surface with a spectral radiance that Kirchhoff labeled I (for specific intensity, the traditional name for spectral radiance).
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- Kirchhoff's postulated spectral radiance I was a universal function, one and the same for all black bodies, only of wavelength and temperature.
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The precise mathematical expression for that universal function I was very much unknown to Kirchhoff, and it was just postulated to exist, until its precise mathematical expression was found in 1900 by Max Planck. It is nowadays referred to as Planck's law.
Then, at each wavelength, for thermodynamic equilibrium in an enclosure, opaque to heat rays, with walls that absorb some radiation at every wavelength:
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- For an arbitrary body radiating and emitting thermal radiation, the ratio E / A between the emissive spectral radiance, E, and the dimensionless absorptive ratio, A, is one and the same for all bodies at a given temperature. That ratio E / A is equal to the emissive spectral radiance I of a perfect black body, a universal function only of wavelength and temperature.
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Read more about this topic: Kirchhoff's Law Of Thermal Radiation
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