Isobaric Process - Defining Enthalpy

Defining Enthalpy

An isochoric process is described by the equation . It would be convenient to have a similar equation for isobaric processes. Substituting the second equation into the first yields

The quantity U + p V is a state function so that it can be given a name. It is called enthalpy, and is denoted as H. Therefore an isobaric process can be more succinctly described as

.

Enthalpy and isobaric specific heat capacity are very useful mathematical constructs, since when analyzing a process in an open system, the situation of zero work occurs when the fluid flows at constant pressure. In an open system, enthalpy is the quantity which is useful to use to keep track of energy content of the fluid.

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