Woad and Indigo
The dye chemical extracted from woad is indigo, the same dye extracted from "true indigo", Indigofera tinctoria, but in a lower concentration. With the European discovery of the seaway to India, great amounts of indigo were imported. Laws were passed in some parts of Europe to protect the woad industry from the competition of the indigo trade. Indigo was proclaimed to rot the yarns as well. "In 1577 the German government officially prohibited the use of indigo, denouncing it as that pernicious, deceitful and corrosive substance, the Devil's dye." "... a recess of the Diet held in 1577 prohibited the use of 'the newly-invented, deceitful, eating and corrosive dye called the devil's dye.'" This prohibition was repeated in 1594 and again in 1603. In France, Henry IV, in an edict of 1609, forbade under pain of death the use of "the false and pernicious Indian drug".
With the development of a chemical process to synthesize the pigment, both the woad and natural indigo industries collapsed in the first years of the 20th century. The last commercial harvest of woad until recent times occurred in 1932, in Lincolnshire, Britain. Small amounts of woad are now grown in UK and France to supply craft dyers. The classic book about woad is The Woad Plant and its Dye by J. B. Hurry, Oxford University Press of 1930, which contains an extensive bibliography.
A method for producing indigo dye from woad is described in the book The History of Woad and the Medieval Woad Vat (1998) ISBN 0-9534133-0-6.
In Germany, there are attempts to use woad to protect wood against decay without dangerous chemicals. Production is also increasing again in the UK for use in inks, particularly for inkjet printers, and dyes, as woad is biodegradable and safe in the environment, unlike many synthetic inks. The plant's presence has its problem however since Isatis tinctoria is viewed as an invasive species in parts of the United States.
Read more about this topic: Isatis Tinctoria