Invariant Mass Vs. Rest Mass
The invariant mass of a system may be greater than sum of rest masses of its separate constituents. For example, rest mass and invariant mass are zero for individual photons even though they may add mass to the invariant mass of systems. For this reason, invariant mass is in general not an additive quantity (although there are a few rare situations where it may be, as is the case when massive particles in a system without potential or kinetic energy can be added to a total mass).
Consider the simple case of two-body system, where object A is moving towards another object B which is initially at rest (in any particular frame of reference). The magnitude of invariant mass of this two-body system (see definition below) is different from the sum of rest mass (i.e. their respective mass when stationary). Even if we consider the same system from center-of-momentum frame, where net momentum is zero, the magnitude of the system's invariant mass is not equal to the sum of the rest masses of the particles within it.
The kinetic energy of such particles and the potential energy of the force fields increase the total energy above the sum of the particle rest masses, and both terms contribute to the invariant mass of the system. The sum of the particle kinetic energies as calculated by an observer is smallest in the center of momentum frame (again, called the "rest frame" if the system is bound).
They will often also interact through one or more of the fundamental forces, giving them a potential energy of interaction, possibly negative.
For an isolated massive system, the center of mass moves in a straight line with a steady sub-luminal velocity. Thus, an observer can always be placed to move along with it. In this frame, which is the center of momentum frame, the total momentum is zero, and the system as a whole may be thought of as being "at rest" if it is a bound system (like a bottle of gas). In this frame, which always exists, the invariant mass of the system is equal to the total system energy (in the zero-momentum frame) divided by c2.
Read more about this topic: Invariant Mass
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