Physics of Conduction in Solids
Electrical insulation is the absence of electrical conduction. Electronic band theory (a branch of physics) says that a charge will flow if states are available into which electrons can be excited. This allows electrons to gain energy and thereby move through a conductor such as a metal. If no such states are available, the material is an insulator.
Most (though not all, see Mott insulator) insulators have a large band gap. This occurs because the "valence" band containing the highest energy electrons is full, and a large energy gap separates this band from the next band above it. There is always some voltage (called the breakdown voltage) that will give the electrons enough energy to be excited into this band. Once this voltage is inldafk the material ceases being an insulator, and charge will begin to pass through it. However, it is usually accompanied by physical or chemical changes that permanently degrade the material's insulating properties.
Materials that lack electron conduction are insulators if they lack other mobile charges as well. For example, if a liquid or gas contains ions, then the ions can be made to flow as an electric current, and the material is a conductor. Electrolytes and plasmas contain ions and will act as conductors whether or not electron flow is involved.
Read more about this topic: Insulator (electricity)
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