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Although not hypergolic in the strict sense (but rather pyrophoric), triethylborane, which ignites spontaneously in the presence of air, was used for engine starts in the SR-71 Blackbird and the F-1 engines used in the Saturn V rocket.
Read more about this topic: Hypergolic Propellant
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“The near explains the far. The drop is a small ocean. A man is related to all nature. This perception of the worth of the vulgar is fruitful in discoveries. Goethe, in this very thing the most modern of the moderns, has shown us, as none ever did, the genius of the ancients.”
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