7-Membered Rings
With 7-membered rings, the heteroatom must be able to provide an empty pi orbital (e.g., boron) for "normal" aromatic stabilization to be available; otherwise, homoaromaticity may be possible. Compounds with one heteroatom include:
Heteroatom | Saturated | Unsaturated |
---|---|---|
Nitrogen | Azepane | Azepine |
Oxygen | Oxepane | Oxepine |
Sulfur | Thiepane | Thiepine |
Those with two heteroatoms include:
Heteroatom | Saturated | Unsaturated |
---|---|---|
Nitrogen | Homopiperazine | Diazepine |
Nitrogen/sulfur | Thiazepine |
Read more about this topic: Heterocyclic Compound
Famous quotes containing the word rings:
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—Administration in the State of Neva, U.S. public relief program. Nevada: A Guide to the Silver State (The WPA Guide to Nevada)