Henry Moseley - Contribution To Physics and Chemistry

Contribution To Physics and Chemistry

In 1913, Moseley observed and measured the X-ray spectra of various chemical elements (mostly metals) that were found by the method of diffraction through crystals. This was a pioneering use of the method of X-ray spectroscopy in physics, using Bragg's diffraction law to determine the X-ray wavelengths. Moseley discovered a systematic mathematical relationship between the wavelengths of the X-rays produced and the atomic numbers of the metals that were used as the targets in X-ray tubes. This has become known as Moseley's law.

Before Moseley's discovery, the atomic numbers (or elemental number) of an element had been thought of as a semi-arbitrary sequential number, based on the sequence of atomic masses, but modified somewhat where chemists found this to be desirable, such as by the great Russian chemist, Dimitri Ivanovich Mendeleev. In his invention of the Periodic Table of the Elements, Mendeleev had interchanged the orders of a few pairs of elements in order to put them in more appropriate places in this table of the elements. For example, the metals cobalt and nickel had been assigned the atomic numbers 27 and 28, respectively, based on their known chemical and physical properties, even though they have nearly the same atomic masses. In fact, the atomic mass of cobalt is slightly larger than that of nickel, which would have placed them in backwards order if they had been placed in the Periodic Table blindly according to atomic mass. Moseley's experiments in X-ray spectroscopy showed directly from their physics that cobalt and nickel have the different atomic numbers, 27 and 28, and that they are placed in the Periodic Table correctly by Moseley's objective measurements of their atomic numbers. Hence, Moseley's discovery demonstrated that the atomic numbers of elements are not just rather arbitrary numbers based on chemistry and the intuition of chemists, but rather, they have a firm experimental basis from the physics of their X-ray spectra.

In addition, Moseley showed that there were gaps in the atomic number sequence at numbers 43, 61, 72, and 75. These spaces are now known, respectively, to be the places of the radioactive synthetic elements technetium and promethium, and also the last two quite rare naturally-occurring stable elements hafnium (discovered 1923) and rhenium (discovered 1925). Nothing about these four elements was known of in Moseley's lifetime, not even their very existence. Based on the intuition of a very experienced chemist, Dimitri Mendeleev had predicted the existence of a missing element in the Periodic Table, which was later found to be filled by technetium, and Bohuslav Brauner had predicted the existence of another missing element in this Table, which was later found to be filled by promethium. Henry Moseley's experiments confirmed these predictions, by showing exactly what the missing atomic numbers were, 43 and 61. In addition, Moseley predicted the two more undiscovered elements, those with the atomic numbers 72 and 75, and gave very strong evidence that there were no other gaps in the Periodic Table between the elements aluminium (atomic number 13) and gold (atomic number 79).

This latter question about the possibility of more undiscovered ("missing") elements had been a standing problem among the chemists of the world, particularly given the existence of the large family of the lanthanide series of rare earth elements. Moseley was able to demonstrate that these lanthanide elements, i.e. lanthanum through lutetium, must have exactly 15 members - no more and no less. The number of elements in the lanthanides had been a question that was very far from being settled by the chemists of the early 20th Century. They could not yet produce pure samples of all the rare-earth elements, even in the form of their salts, and in some cases they were unable to distinguish between mixtures of two very similar (adjacent) rare-earth elements from the nearby pure metals in the Periodic Table. For example, there was a so-called "element" that was even given the chemical name of "didymium". "Didymium" was found some years later to be simply a mixture of two genuine rare-earth elements, and these were given the names neodymium and praseodymium, meaning "new twin" and "green twin". Also, the method of separating the rare-earth elements by the method of ion exchange had not been invented yet in Moseley's time.

Moseley's method in early X-ray spectroscopy was able to sort out the above chemical problems promptly, some of which had occupied chemists for a number of years. Moseley also predicted the existence of element 61, a lanthanide whose existence was previously unsuspected. Quite a few years later, this element 61 was created artificially in nuclear reactors and was named promethium.