Explanation
Green flashes are enhanced by mirage, which increase the density gradient in the atmosphere and therefore, increase refraction. A green flash is more likely to be seen in clear air, when more of the light from the setting sun reaches the observer without being scattered. One might expect to see a blue flash, but the blue is preferentially scattered out of the line of sight, and remaining light ends up looking green.
With slight magnification a green rim on the top of the solar disk may be seen on most clear-day sunsets, although the flash or ray effects require a stronger layering of the atmosphere and a mirage, which serves to magnify the green from a fraction of a second to a couple of seconds.
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