Glass Fiber - Chemistry

Chemistry

The basis of textile-grade glass fibers is silica, SiO₂. In its pure form it exists as a polymer, (SiO₂)_n. It has no true melting point but softens up to 1200°C, where it starts to degrade. At 1713°C, most of the molecules can move about freely. If the glass is extruded and cooled quickly at this temperature, it will be unable to form an ordered structure. In the polymer it forms SiO₄ groups which are configured as a tetrahedron with the silicon atom at the center, and four oxygen atoms at the corners. These atoms then form a network bonded at the corners by sharing the oxygen atoms.

The vitreous and crystalline states of silica (glass and quartz) have similar energy levels on a molecular basis, also implying that the glassy form is extremely stable. In order to induce crystallization, it must be heated to temperatures above 1200°C for long periods of time.

Although pure silica is a perfectly viable glass and glass fiber, it must be worked with at very high temperatures, which is a drawback unless its specific chemical properties are needed. It is usual to introduce impurities into the glass in the form of other materials to lower its working temperature. These materials also impart various other properties to the glass that may be beneficial in different applications. The first type of glass used for fiber was soda lime glass or A glass. It is not very resistant to alkali. A new type, E-glass, was formed; this is an alumino-borosilicate glass that is alkali free (<2%). This was the first glass formulation used for continuous filament formation. E-glass still makes up most of the glass fiber production in the world. Its particular components may differ slightly in percentage, but must fall within a specific range. The letter E is used because it was originally for electrical applications. S-glass is a high-strength formulation for use when tensile strength is the most important property. C-glass was developed to resist attack from chemicals, mostly acids that destroy E-glass. T-glass is a North American variant of C-glass. A-glass is an industry term for cullet glass, often bottles, made into fiber. AR-glass is alkali-resistant glass. Most glass fibers have limited solubility in water but are very dependent on pH. Chloride ions will also attack and dissolve E-glass surfaces.

E-glass does not really melt, but softens instead, the softening point being "the temperature at which a 0.55–0.77 mm diameter fiber 235 mm long, elongates under its own weight at 1 mm/min when suspended vertically and heated at the rate of 5°C per minute". The strain point is reached when the glass has a viscosity of 1014.5 poise. The annealing point, which is the temperature where the internal stresses are reduced to an acceptable commercial limit in 15 minutes, is marked by a viscosity of 1013 poise.