In thermodynamics, the fundamental thermodynamic relation is generally expressed as an infinitesimal change in internal energy in terms of infinitesimal changes in entropy, and volume for a closed system in thermal equilibrium in the following way.
Here, U is internal energy, T is absolute temperature, S is entropy, P is pressure, and V is volume.
This is only one expression of the fundamental thermodynamic relation. It may be expressed in other ways, using different variables (e.g. using thermodynamic potentials). For example, the fundamental relation may be expressed in terms of the Helmholtz free energy (F) as:
Read more about Fundamental Thermodynamic Relation: Derivation From The First and Second Laws of Thermodynamics, Derivation From Statistical Mechanical Principles
Famous quotes containing the words fundamental and/or relation:
“One of the fundamental reasons why so many doctors become cynical and disillusioned is precisely because, when the abstract idealism has worn thin, they are uncertain about the value of the actual lives of the patients they are treating. This is not because they are callous or personally inhuman: it is because they live in and accept a society which is incapable of knowing what a human life is worth.”
—John Berger (b. 1926)
“Among the most valuable but least appreciated experiences parenthood can provide are the opportunities it offers for exploring, reliving, and resolving one’s own childhood problems in the context of one’s relation to one’s child.”
—Bruno Bettelheim (20th century)