In thermodynamics, the fundamental thermodynamic relation is generally expressed as an infinitesimal change in internal energy in terms of infinitesimal changes in entropy, and volume for a closed system in thermal equilibrium in the following way.
Here, U is internal energy, T is absolute temperature, S is entropy, P is pressure, and V is volume.
This is only one expression of the fundamental thermodynamic relation. It may be expressed in other ways, using different variables (e.g. using thermodynamic potentials). For example, the fundamental relation may be expressed in terms of the Helmholtz free energy (F) as:
Read more about Fundamental Thermodynamic Relation: Derivation From The First and Second Laws of Thermodynamics, Derivation From Statistical Mechanical Principles
Famous quotes containing the words fundamental and/or relation:
“In a period of a people’s life that bears the designation “transitional,” the task of a thinking individual, of a sincere citizen of his country, is to go forward, despite the dirt and difficulty of the path, to go forward without losing from view even for a moment those fundamental ideals on which the entire existence of the society to which he belongs is built.”
—Ivan Sergeevich Turgenev (1818–1883)
“The problem of the twentieth century is the problem of the color-line—the relation of the darker to the lighter races of men in Asia and Africa, in America and the islands of the sea. It was a phase of this problem that caused the Civil War.”
—W.E.B. (William Edward Burghardt)