Free Electron Model - Fermi Level

Fermi Level

According to the Pauli principle, the electrons in the ground state occupy all the lowest-energy states, up to some Fermi energy . Since the energy is given by

,

this corresponds to occupying all the states with wave vectors, where is so-called Fermi wave vector, given by

,

where is the total number of electrons in the system, and V is the total volume. The Fermi energy is then

In a nearly-free-electron model of a -valent metal, one can replace with, where is the total number of metal ions.

Read more about this topic:  Free Electron Model

Famous quotes containing the word level:

    Adults understandably assume that the level of verbal proficiency a five-year-old displays represents his level of proficiency in all areas of functioning—if he talks like an adult, he must think and feel like one. However, five-year-olds,... belie the promise of adult-like behavior with their child-like, impulsive actions.
    Dorothy H. Cohen (20th century)