Principles of Operation
The fundamental means for conversion of electrical energy into radiant energy in a fluorescent lamp relies on inelastic scattering of electrons. An incident electron collides with an atom in the gas. If the free electron has enough kinetic energy, it transfers energy to the atom's outer electron, causing that electron to temporarily jump up to a higher energy level. The collision is 'inelastic' because a loss of kinetic energy occurs.
This higher energy state is unstable, and the atom will emit an ultraviolet photon as the atom's electron reverts to a lower, more stable, energy level. Most of the photons that are released from the mercury atoms have wavelengths in the ultraviolet (UV) region of the spectrum, predominantly at wavelengths of 253.7 and 185 nanometers (nm). These are not visible to the human eye, so they must be converted into visible light. This is done by making use of fluorescence. Ultraviolet photons are absorbed by electrons in the atoms of the lamp's interior fluorescent coating, causing a similar energy jump, then drop, with emission of a further photon. The photon that is emitted from this second interaction has a lower energy than the one that caused it. The chemicals that make up the phosphor are chosen so that these emitted photons are at wavelengths visible to the human eye. The difference in energy between the absorbed ultra-violet photon and the emitted visible light photon goes toward heating up the phosphor coating.
When the light is turned on, the electric power heats up the cathode enough for it to emit electrons (thermionic emission). These electrons collide with and ionize noble gas atoms inside the bulb surrounding the filament to form a plasma by the process of impact ionization. As a result of avalanche ionization, the conductivity of the ionized gas rapidly rises, allowing higher currents to flow through the lamp.
The fill gas helps determine the operating electrical characteristics of the lamp, but does not give off light itself. The fill gas effectively increases the distance that electrons travel through the tube, which allows an electron a greater chance of interacting with a mercury atom. Argon atoms, excited to a metastable state by impact of an electron, can impart this energy to a neutral mercury atom and ionize it, described as the Penning effect. This has the benefit of lowering the breakdown and operating voltage of the lamp, compared to other possible fill gases such as krypton.
Read more about this topic: Fluorescent Lamp
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