History
Arnold Sommerfeld introduced the fine-structure constant in 1916, as part of his theory of the relativistic deviations of atomic spectral lines from the predictions of the Bohr model. The first physical interpretation of the fine-structure constant α was as the ratio of the velocity of the electron in the first circular orbit of the relativistic Bohr atom to the speed of light in the vacuum. Equivalently, it was the quotient between the maximum angular momentum allowed by relativity for a closed orbit, and the minimum angular momentum allowed for it by quantum mechanics. It appears naturally in Sommerfeld's analysis, and determines the size of the splitting or fine-structure of the hydrogenic spectral lines.
The fine-structure constant so intrigued physicist Wolfgang Pauli that he collaborated with psychiatrist Carl Jung in an extraordinary quest to understand its significance.
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